Carbocation & Ketene Chemistry
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CARBOCATION CHEMISTRY; KETENE CHEMISTRY; ORGANIC REACTION MECHANISM. Expert has been a creative scientist covering a broad range of topics in organic chemistry for the past 30 years. Early in his career, he became an established authority on steric effects. He also made major contributions to ketone enolization, substituent effects, free radical cyclization, organofluorine compounds, and acid-catalyzed hydration of alkenes. More recently, Expert has been a pioneer in the study of destabilized carbocations. A leader in the renaissance in ketene chemistry, Expert has systematized the understanding of the entire area and has transformed bisketenes from laboratory curiosities to important chemical intermediates.